Test with Sulphate Ions user 12 years ago Test with Sulphate Ions Out of the 10 cations, only calcium ions and lead(II) ions will form a precipitate with sulphate ions.This is because both calcium sulphate and lead(II) sulphate are insoluble in water.The chemical reaction is a double decomposition reaction.Pb2+ + SO42- → PbSO4Ca2+ + SO42- → CaSO4H2SO4 or Na2SO4Na+–Ca2+White precipitate.Mg2+–Al3+–Zn2+–Pb2+White precipitate.Fe2+–Fe3+–Cu2+–NH4+–